Chlorine molecules from pool water interacting with scalp surface and hair strands

Chlorine: the Guest That May Crash the Pool Party

Dive into how pool exposure affects your hair, and learn what makes your scalp stay afloat this summer.

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A refreshing dip in the pool is one of summer’s joys—but for your scalp and hair, chlorine and pool disinfectants can quietly cause chaos. These chemicals are essential for water hygiene but may strip natural oils, disrupt the scalp’s pH, weaken the barrier function, and damage the hair shaft.

What Chlorine Does to the Scalp

1. Lipid Barrier Breakdown
Chlorine acts as an oxidising agent, breaking down sebum—your scalp’s natural oil. This compromises hydration and leaves the scalp exposed to irritants and water loss.

Applying protective hair oil before swimming in pool
2. pH DisruptionMost pool water sits at pH 7.2–7.8, more alkaline than your scalp’s natural ~5.5. This pH mismatch can weaken the acid mantle, leaving your scalp more prone to dryness, imbalance, and inflammation.

3. Increased TEWL (Transepidermal Water Loss)
With disrupted lipids and raised pH, water evaporates faster from the scalp, leading to tightness, flaking, and rebound oiliness.

4. Microbiome Disturbance
Chlorine doesn’t discriminate. It affects beneficial scalp microbes too—especially with repeated exposure—potentially triggering sensitivity, itching, or dandruff.

How Pool Chemicals Affect Your Hair

scalp hydration after swimming

Cuticle Damage
Chlorine opens up the cuticle, the protective outer layer of your hair, increasing porosity. The vulnerable inner cortex is exposed to friction and oxidation, leading to frizz, split ends, dullness, and breakage.

Protein Degradation
Electron microscopy studies show that chlorine degrades keratin, especially the cysteine-rich regions that maintain strength and elasticity. Result: weakened, fragile strands.

Oxidative Colour Fading
Chlorine accelerates the degradation of melanin (natural pigment) and causes oxidative stress—bad news for coloured hair. In blondes, chlorine can also react with copper ions in water, resulting in a greenish tinge.

Signs of Chlorine Reaction

  • Flaky or tight scalp a few hours post-swim
  • Itching or tingling along the hairline
  • Rough-feeling scalp despite washing
  • Dull, rough or limp hair the next day

Scalp & Hair Protection for Swimmers

Dakmatter  | Diagram of chlorine exposure disrupting scalp barrier and causing moisture loss in hair

Before Swimming:

  • Wet your hair with clean water—this saturates the cuticle, reducing chlorine absorption.
  • Mist scalp with Dakmatter 300 Aroma Tonic to support pH and microbiota balance.
  • Apply a thin layer of Dakmatter 201 Conditioning Oil Serum to dry scalp and hair to form a breathable barrier.
  • Wear a swim cap to further limit exposure.

After Swimming:

Avoid:

  • Harsh surfactants (like SLS) or clarifying shampoos
  • Vigorous scrubbing or exfoliation post-swim
  • Ignoring subtle signs of irritation, early detection prevents lasting damage

The Takeaway

Illustration showing how chlorine in pool water weakens the scalp barrier and damages hair

You don’t have to give up pool time to keep your scalp and hair healthy. With the right prep and aftercare focused on barrier protection, hydration, and pH support, you can enjoy your swim without compromising your crown. PS. The Classic that never goes out of effect and fashion: Always protect scalp and hair with a hat or scarf while not being in the water. It may be life-changing... Knowledge is power!

author
Alexa Wolf
Advanced Formulator Chemist
https://dakmatter.com

As a formulator and co-founder of Dakmatter, I geek out over green chemistry, the unchartered power of medicinal plants (how little we know about them) and, cosmetic equality and diversity. I also love teaching the science behind beauty and exploring the incredible journey of Black hair history. Because knowledge is power — and cosmetic health is for everyone!